| Date | Home | Away | Result |
|---|---|---|---|
| 10/3/23 12:00 PM | AD Alcorcon | Albacete Balompie | 1-2 |
| 10/3/23 12:00 PM | UD Levante | FC Villarreal B | 1-1 |
| 10/3/23 2:30 PM | CD Teneriffa | Racing Santander | 2-0 |
| 10/4/23 12:00 PM | Eldense | Real Valladolid | 0-1 |
| 10/4/23 12:00 PM | Real Oviedo | SD Huesca | 1-0 |
| 10/4/23 2:30 PM | Sporting Gijon | FC Elche | 2-0 |
| 10/4/23 2:30 PM | Burgos CF | CD Leganes | 1-0 |
| 10/5/23 12:00 PM | Andorra CF | Real Saragossa | 0-1 |
| 10/5/23 12:00 PM | CD Mirandes | SD Eibar | 1-3 |
| 10/5/23 2:30 PM | Racing de Ferrol | SD Amorebieta | 1-0 |
| 10/5/23 2:30 PM | FC Cartagena | Espanyol Barcelona | 0-2 |