| Date | Home | Away | Result |
|---|---|---|---|
| 8/18/23 12:30 PM | RCD Mallorca | FC Villarreal | 0-1 |
| 8/18/23 2:30 PM | FC Valencia | UD Las Palmas | 1-0 |
| 8/19/23 10:00 AM | Real Sociedad | Celta Vigo | 1-1 |
| 8/19/23 12:30 PM | UD Almeria | Real Madrid | 1-3 |
| 8/19/23 2:30 PM | CA Osasuna | Athletic Bilbao | 0-2 |
| 8/20/23 12:00 PM | FC Girona | FC Getafe | 3-0 |
| 8/20/23 12:30 PM | FC Barcelona | FC Cadiz | 2-0 |
| 8/20/23 2:30 PM | Real Betis Sevilla | Atletico Madrid | 0-0 |
| 8/21/23 12:00 PM | Deportivo Alaves | FC Sevilla | 4-3 |
| 8/21/23 2:30 PM | FC Granada | Rayo Vallecano | 0-2 |