| Date | Home | Away | Result |
|---|---|---|---|
| 10/20/23 2:00 PM | CA Osasuna | FC Granada | 2-0 |
| 10/21/23 7:00 AM | Real Sociedad | RCD Mallorca | 1-0 |
| 10/21/23 9:15 AM | FC Getafe | Real Betis Sevilla | 1-1 |
| 10/21/23 11:30 AM | FC Sevilla | Real Madrid | 1-1 |
| 10/21/23 2:00 PM | Celta Vigo | Atletico Madrid | 0-3 |
| 10/22/23 7:00 AM | UD Las Palmas | Rayo Vallecano | 0-1 |
| 10/22/23 9:15 AM | FC Girona | UD Almeria | 5-2 |
| 10/22/23 11:30 AM | FC Villarreal | Deportivo Alaves | 1-1 |
| 10/22/23 2:00 PM | FC Barcelona | Athletic Bilbao | 1-0 |
| 10/23/23 2:00 PM | FC Valencia | FC Cadiz | 2-0 |