| Date | Home | Away | Result |
|---|---|---|---|
| 10/31/23 12:00 PM | FC 08 Homburg | SpVgg Greuther Fürth | 2-1 |
| 10/31/23 12:00 PM | FC St. Pauli | FC Schalke 04 | 2-1a.e.t |
| 10/31/23 12:00 PM | VfB Stuttgart | 1. FC Union Berlin | 1-0 |
| 10/31/23 12:00 PM | VfL Wolfsburg | RB Leipzig | 1-0 |
| 10/31/23 2:45 PM | Bor. Mönchengladbach | 1. FC Heidenheim 1846 | 3-1 |
| 10/31/23 2:45 PM | Arminia Bielefeld | Hamburger SV | 4-5a.PSO |
| 10/31/23 2:45 PM | 1. FC Kaiserslautern | 1. FC Köln | 3-2 |
| 10/31/23 2:45 PM | SpVgg Unterhaching | Fortuna Düsseldorf | 3-6a.e.t |
| 11/1/23 12:00 PM | Borussia Dortmund | 1899 Hoffenheim | 1-0 |
| 11/1/23 12:00 PM | Holstein Kiel | 1. FC Magdeburg | 6-7a.PSO |
| 11/1/23 12:00 PM | SC Freiburg | SC Paderborn 07 | 1-3 |
| 11/1/23 12:00 PM | SV Sandhausen | Bayer 04 Leverkusen | 2-5 |
| 11/1/23 2:45 PM | Hertha BSC | FSV Mainz 05 | 3-0 |
| 11/1/23 2:45 PM | 1. FC Saarbrücken | FC Bayern Munich | 2-1 |
| 11/1/23 2:45 PM | 1. FC Nürnberg | FC Hansa Rostock | 3-2a.e.t |
| 11/1/23 2:45 PM | FC Viktoria Köln | Eintracht Frankfurt | 0-2 |