| Date | Home | Away | Result |
|---|---|---|---|
| 9/8/23 2:00 PM | UD Levante | Espanyol Barcelona | 1-4 |
| 9/9/23 9:15 AM | Burgos CF | SD Eibar | 1-0 |
| 9/9/23 11:30 AM | Real Oviedo | Sporting Gijon | 0-0 |
| 9/9/23 2:00 PM | CD Teneriffa | Albacete Balompie | 2-0 |
| 9/9/23 2:00 PM | CD Leganes | SD Huesca | 2-0 |
| 9/10/23 9:15 AM | Racing Santander | SD Amorebieta | 1-0 |
| 9/10/23 9:15 AM | Racing de Ferrol | FC Villarreal B | 2-2 |
| 9/10/23 11:30 AM | CD Mirandes | Andorra CF | 4-3 |
| 9/10/23 11:30 AM | FC Cartagena | Real Saragossa | 1-3 |
| 9/10/23 2:00 PM | Real Valladolid | FC Elche | 1-1 |
| 9/11/23 2:00 PM | Eldense | AD Alcorcon | 2-2 |