| Date | Home | Away | Result |
|---|---|---|---|
| 9/26/23 12:00 PM | FC Sevilla | UD Almeria | 5-1 |
| 9/26/23 2:30 PM | RCD Mallorca | FC Barcelona | 2-2 |
| 9/27/23 12:00 PM | Athletic Bilbao | FC Getafe | 2-2 |
| 9/27/23 12:00 PM | FC Villarreal | FC Girona | 1-2 |
| 9/27/23 12:00 PM | Real Madrid | UD Las Palmas | 2-0 |
| 9/27/23 2:30 PM | FC Cadiz | Rayo Vallecano | 0-0 |
| 9/27/23 2:30 PM | FC Valencia | Real Sociedad | 0-1 |
| 9/28/23 12:00 PM | FC Granada | Real Betis Sevilla | 1-1 |
| 9/28/23 12:00 PM | Celta Vigo | Deportivo Alaves | 1-1 |
| 9/28/23 2:30 PM | CA Osasuna | Atletico Madrid | 0-2 |