| Date | Home | Away | Result |
|---|---|---|---|
| 9/22/23 2:00 PM | Deportivo Alaves | Athletic Bilbao | 0-2 |
| 9/23/23 7:00 AM | FC Girona | RCD Mallorca | 5-3 |
| 9/23/23 9:15 AM | CA Osasuna | FC Sevilla | 0-0 |
| 9/23/23 11:30 AM | FC Barcelona | Celta Vigo | 3-2 |
| 9/23/23 2:00 PM | UD Almeria | FC Valencia | 2-2 |
| 9/24/23 7:00 AM | Real Sociedad | FC Getafe | 4-3 |
| 9/24/23 9:15 AM | Rayo Vallecano | FC Villarreal | 1-1 |
| 9/24/23 11:30 AM | Real Betis Sevilla | FC Cadiz | 1-1 |
| 9/24/23 11:30 AM | UD Las Palmas | FC Granada | 1-0 |
| 9/24/23 2:00 PM | Atletico Madrid | Real Madrid | 3-1 |