| Date | Home | Away | Result |
|---|---|---|---|
| 8/25/23 12:30 PM | UD Las Palmas | Real Sociedad | 0-0 |
| 8/25/23 2:30 PM | Celta Vigo | Real Madrid | 0-1 |
| 8/26/23 12:00 PM | FC Cadiz | UD Almeria | 1-1 |
| 8/26/23 12:30 PM | FC Granada | RCD Mallorca | 3-2 |
| 8/26/23 2:30 PM | FC Sevilla | FC Girona | 1-2 |
| 8/27/23 10:30 AM | FC Villarreal | FC Barcelona | 3-4 |
| 8/27/23 12:30 PM | FC Valencia | CA Osasuna | 1-2 |
| 8/27/23 2:30 PM | Athletic Bilbao | Real Betis Sevilla | 4-2 |
| 8/28/23 12:30 PM | FC Getafe | Deportivo Alaves | 1-0 |
| 8/28/23 2:30 PM | Rayo Vallecano | Atletico Madrid | 0-7 |